A Luna Wolf Captain of the IXth Company.

A Tactical Marine.

These were painted in the following fashion.
Spray undercoated black, then a basecoats of Astronomican Gray for the white (blacklining all the way), Chaos Black for the Trim on the Shoulder Pads, Scab Red for the Red, Burnished Gold and Boltgun Metal as appropriate.
All of the Black parts were then washed with Black Wash, Gold with Chestnut Wash, Boltgun metal with Armour wash.
A mix of Astronomican Gray and Skull White (I just mixed this by eye) was then painted over the Astro Gray, Crimson gore over the Scab Red, and touched up parts of the metal with Burnished gold and Mithral Silver.
The parchment was basecoated Vomit brown, Washed with Flesh wash, a coat of bleached bone leaving the darker colours in the recesses, with a final coat of Skull white. Writing is just black ink.
I highlighted the White areas with a light coat of Skull White, Red areas with Blood Red, Gold with Shining Gold, Black with a light dash of Adeptus Battlegrey.
For the eyes think eldar gemstone technique.
Once the Eyes and Wax seals were dry they were given a coat of Gloss varnish.
Transfers were then applied.